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膜分离 5

反渗透 3

渗透汽化 3

双极板 2

反渗透膜 2

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吸附 2

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膜材料 2

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Modeling of Ce(IV) transport through a dispersion flat combined liquid membrane with carrier P507

Liang PEI,Liming WANG,Zhanying MA

《环境科学与工程前沿(英文)》 2014年 第8卷 第4期   页码 503-509 doi: 10.1007/s11783-013-0540-1

摘要: A mathematical model for the transport of Ce(IV) from hydrochloric acid solutions through dispersion flat combined liquid membrane (DFCLM) with contain 2-ethyl hexyl phosphonic acid-mono-2-ethyl hexyl ester (P507) as the carrier, dissolved in kerosene as the membrane solution have been studied. This process of facilitated transport, based on membrane technology, is a variation on the conventional technique of solvent extraction and may be described mathematically using Fick’s second law. The equations for transport velocity are derived considering the diffusion of P507 and its metallic complexes through the liquid membrane. In this work, the system is considered to be in a transient state, and chemical reaction between Ce(IV) and the carrier to take place only at the solvent–aqueous interfaces. Model concentration profiles are obtained for the Ce(IV), from which extraction velocities are predicted. The experimental and simulated Ce(IV) extractions showed similar tendencies for a high Ce(IV) concentration and acidity case.The model results indicate that high initial Ce(IV) concentrations and acidity both have detrimental effects on Ce(IV) extraction and stripping. The diffusion coefficient of Ce(IV) in the membrane and the thickness of diffusion layer between feed phase and membrane phase are obtained and the values are 6.31 × 10 m ·s and 31.2 μm, respectively. The results are in good agreement with experimental results.

关键词: Dispersion flat combined liquid membrane (DFCLM)     dispersion phase     feed phase     2-ethyl hexyl phosphonic acid-mono-2-ethyl hexyl ester     Ce (IV)    

Enhanced cross-flow filtration with flat-sheet ceramic membranes by titanium-based coagulation for membrane

《环境科学与工程前沿(英文)》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1531-x

摘要:

• Ceramic membrane filtration showed high performance for surface water treatment.

关键词: Ceramic membrane     Coagulation     Polytitanium chloride     Membrane fouling    

Electro-assisted CNTs/ceramic flat sheet ultrafiltration membrane for enhanced antifouling and separation

Shuo Wei, Lei Du, Shuo Chen, Hongtao Yu, Xie Quan

《环境科学与工程前沿(英文)》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1303-4

摘要: Abstract • A stable and electroconductive CNTs/ceramic membrane was fabricated. • The membrane with the electro-assistance exhibited optimal fouling mitigation. • The removal efficiency was improved by the -2.0 V electro-assistance. • Electro-assisted filtration is energy-saving than that of commercial membrane. Ultrafiltration is employed as an important process for water treatment and reuse, which is of great significance to alleviate the shortage of water resources. However, it suffers from severe membrane fouling and the trade-off between selectivity and permeability. In this work, a CNTs/ceramic flat sheet ultrafiltration membrane coupled with electro-assistance was developed for improving the antifouling and separation performance. The CNTs/ceramic flat sheet membrane was fabricated by coating cross-linked CNTs on ceramic membrane, featuring a good electroconductivity of 764.75 S/m. In the filtration of natural water, the permeate flux of the membrane with the cell voltage of -2.0 V was 1.8 times higher than that of the membrane without electro-assistance and 5.7-fold greater than that of the PVDF commercial membrane. Benefiting from the electro-assistance, the removal efficiency of the typical antibiotics was improved by 50%. Furthermore, the electro-assisted membrane filtration process showed 70% reduction in energy consumption compared with the filtration process of the commercial membrane. This work offers a feasible approach for membrane fouling mitigation and effluent quality improvement and suggests that the electro-assisted CNTs/ceramic membrane filtration process has great potential in the application of water treatment.

关键词: Ultrafiltration     Electro-assistance     CNTs     Membrane fouling mitigation    

Experimental study on combined buoyant-thermocapillary flow along with rising liquid film on the surface

Manuel J. GOMES, Ning MEI

《能源前沿(英文)》 2020年 第14卷 第1期   页码 114-126 doi: 10.1007/s11708-017-0483-5

摘要: Temperature distribution and variation with time has been considered in the analysis of the influences of the initial level of immersion of a horizontal metallic mesh tube in the liquid on combined buoyant and thermo-capillary flow. The combined flow occurs along with the rising liquid film flow on the surface of a horizontal metallic mesh tube. Three different levels of immersion of the metallic mesh tube in the liquid have been tested. Experiments of 60 min in duration have been performed using a heating metallic tube with a diameter of 25 mm and a length of 110 mm, sealed outside with a metallic mesh of 178 mm by 178 mm, and distilled water. These reveal two distinct flow patterns. Thermocouples and infrared thermal imager are utilized to measure the temperature. The level of the liquid free surface relative to the lower edge of the tube is measured as angle . The results show that for a smaller angle, or a low level of immersion, with a relatively low heating power, it is possible to near fully combine the upwards buoyant flow with the rising liquid film flow. In this case, the liquid is heated only in the vicinity of the tube, while the liquid away from the flow region experiences small changes in temperature and the system approaches steady conditions. For larger angles, or higher levels of immersion, a different flow pattern is noticed on the liquid free surface and identified as the thermo-capillary (Marangoni) flow. The rising liquid film is also present. The higher levels of immersion cause a high temperature gradient in the liquid free surface region and promote thermal stratification; therefore the system could not approach steady conditions.

关键词: rising liquid film     combined flow     thermo-capillary flow     buoyant flow     metallic mesh tube     horizontal tube    

Residence time distribution and modeling of the liquid phase in an impinging stream reactor

Xingjun WANG, Xianhui HU, Lishun HU, Guangsuo YU, Fuchen WANG,

《化学科学与工程前沿(英文)》 2010年 第4卷 第3期   页码 353-359 doi: 10.1007/s11705-009-0262-x

摘要: Based on some experimental investigations of liquid phase residence time distribution (RTD) in an impinging stream reactor, a two-dimensional plug-flow dispersion model for predicting the liquid phase RTD in the reactor was proposed. The calculation results of the model can be in good agreement with the experimental RTD under different operating conditions. The axial liquid dispersion coefficient increases monotonously with the increasing liquid flux, but is almost independent of gas flux. As the liquid flux and the gas flux increase, the liquid dispersion coefficient of center-to-wall decreases. The axial liquid dispersion coefficient is much larger than that of center-to-wall, which indicates that the liquid RTD is dominated mainly by axial liquid dispersion in the impinging stream reactor.

关键词: RTD     liquid dispersion     reactor     liquid     independent    

Preparation and characterization of PVDF-PFSA flat sheet ultrafiltration membranes

Jiquan MA, Junhong ZHAO, Zhongbin REN, Lei LI

《化学科学与工程前沿(英文)》 2012年 第6卷 第3期   页码 301-310 doi: 10.1007/s11705-012-1204-6

摘要: High performance polyvinylidene fluoride (PVDF) flat sheet ultrafiltration (UF) membranes have been prepared by an immersion precipitation phase inversion method using perfluorosulfonic acid (PFSA) as a pore former and as a hydrophilic component of the membranes and polyethylene glycol ( = 400) (PEG400) as a pore forming agent. The effects of the presence of PEG and the concentration of the PFSA on the phase separation of the casting solutions and on the morphologies and performance of UF membranes including their porosity, water flux, rejection of bovine serum albumin (BSA) protein, and anti-fouling property were investigated. Phase diagrams, viscosities and the phase separations upon exposure to water vapor showed that both PEG400 and PFSA promoted demixing of the casting solution. Scanning electron microscopy measurements showed that the PVDF-PFSA blend membranes had more macropores and finger-like structures than the native PVDF membranes. The PVDF-PFSA membrane (5 wt-% PEG400+ 5 wt-% PFSA) had a pure water flux of 141.7 L/m ·h, a BSA rejection of 90.1% and a relative pure water flux reduction (RFR) of 15.28%. These properties were greatly superior to those of the native PVDF membrane (pure water flux of 5.6 L/m ·h, BSA rejection of 96.3% and RFR of 42.86%).

关键词: polyvinylidene fluoride     perfluorosulfonic acid     polyethylene glycol     flat sheet membrane     ultrafiltration    

A combined control strategy using tuned liquid dampers to reduce displacement demands of base-isolated

Parham SHOAEI, Houtan Tahmasebi OROMI

《结构与土木工程前沿(英文)》 2019年 第13卷 第4期   页码 890-903 doi: 10.1007/s11709-019-0524-8

摘要: This paper investigates a hybrid structural control system using tuned liquid dampers (TLDs) and lead-rubber bearing (LRB) systems for mitigating earthquake-induced vibrations. Furthermore, a new approach for taking into account the uncertainties associated with the steel shear buildings is proposed. In the proposed approach, the probabilistic distributions of the stiffness and yield properties of stories of a set of reference steel moment frame structures are derived through Monte-Carlo sampling. The approach is applied to steel shear buildings isolated with LRB systems. The base isolation systems are designed for different target base displacements by minimizing a relative performance index using Genetic Algorithm. Thereafter, the base-isolated structures are equipped with TLDs and a combination of the base and TLD properties is sought by which the maximum reduction occurs in the base displacement without compromising the performance of the system. In addition, the effects of TLD properties on the performance of the system are studied through a parametric study. Based on the analyses results, the base displacement can be reduced 23% by average, however, the maximum reduction can go beyond 30%.

关键词: tuned liquid damper     lead-rubber bearing system     probabilistic framework     steel shear building     relative performance index     Monte-Carlo sampling    

Cesium removal from radioactive wastewater by adsorption and membrane technology

《环境科学与工程前沿(英文)》 2023年 第18卷 第3期 doi: 10.1007/s11783-024-1798-1

摘要:

● Removal of cesium from radioactive wastewater is still a challenging.

关键词: Cesium     Adsorption     Membrane separation     Advanced liquid processing system     Fukushima nuclear accident    

Ionic liquid modified Pt/C electrocatalysts for cathode application in proton exchange membrane fuel

Huixin Zhang, Jinying Liang, Bangwang Xia, Yang Li, Shangfeng Du

《化学科学与工程前沿(英文)》 2019年 第13卷 第4期   页码 695-701 doi: 10.1007/s11705-019-1838-8

摘要: The modification of Pt/C catalyst by using ionic liquids to improve their catalyst activities has been reported by many researchers, but their practical behavior in operating fuel cells is still unknown. In this work, we study the ionic liquid modified Pt/C nanoparticle catalysts within cathodes for proton exchange membrane fuel cells. The influence of the ionic liquid amount, adsorption times and dispersing solvents are investigated. The experiment results show the best performance enhancement is achieved through two-time surface modification with 2 wt-% ionic liquid solution. The mechanisms are explored with the attribution to the high oxygen solubility in the ionic liquid enabling an improved oxygen diffusion in micropores and to good hydrophobicity facilitating water expelling from the active sites in fuel cell operation.

关键词: ionic liquid     PEMFC     electrode     oxygen reduction reaction     electrocatalyst     adsorption    

Development of combined coagulation-hydrolysis acidification-dynamic membrane bioreactor system for treatment

Xue Shen, Lei Lu, Baoyu Gao, Xing Xu, Qinyan Yue

《环境科学与工程前沿(英文)》 2019年 第13卷 第1期 doi: 10.1007/s11783-019-1093-8

摘要:

• We created a combined system for treating oilfield polymer-flooding wastewater.

• The system was composed of coagulation, hydrolysis acidification and DMBR.

• Coagulant integrated with demulsifier dominated the removal of crude oil.

• The DMBR proceed efficiently without serious membrane fouling.

关键词: Coagulation     Hydrolysis acidification     Dynamic membrane bioreactor     Polymer flooding    

Numerical simulation of three-dimensional gas/liquid two-phase flow in a proton exchange membrane fuel

ZHUGE Weilin, ZHANG Yangjun, LAO Xingsheng, CHEN Xiao, MING Pingwen

《能源前沿(英文)》 2007年 第1卷 第3期   页码 305-310 doi: 10.1007/s11708-007-0044-4

摘要: Investigation into the formation and transport of liquid water in proton exchange membrane fuel cells (PEMFCs) is the key to fuel cell water management. A three-dimensional gas/liquid two-phase flow and heat transfer model is developed based on the multiphase mixture theory. The reactant gas flow, diffusion, and chemical reaction as well as the liquid water transport and phase change process are modeled. Numerical simulations on liquid water distribution and its effects on the performance of a PEMFC are conducted. Results show that liquid water distributes mostly in the cathode, and predicted cell performance decreases quickly at high current density due to the obstruction of liquid water to oxygen diffusion. The simulation results agree well with experimental data.

关键词: diffusion     gas/liquid two-phase     management     exchange     transfer    

Effect of a commercial dispersion of multi walled carbon nanotubes on the hydration of an oil well cementing

Ocar Aurelio MENDOZA REALES,William C.PEARL Jr,Maria D. M. PAIVA,CristianeR. MIRANDA,Romildo Dias TOLEDO FILHO

《结构与土木工程前沿(英文)》 2016年 第10卷 第2期   页码 174-179 doi: 10.1007/s11709-015-0324-8

摘要: This work studies the influence of a commercial dispersion of multi wall carbon nanotubes (MWCNT) on the hydration of a class G cement paste, at room and elevated down-hole temperatures. The MWCNT dispersion was produced with a solids concentration of 3.0 % by mass and an anionic surfactant as dispersing agent. Cement pastes with water-to-cement ratio of 0.45 and additions of solid MWCNT by mass of cement up to 0.50 % were studied. Isothermal calorimetry results showed a clear retardation of the hydration of cement caused by the surfactant contained in the MWCNT dispersion. Nevertheless, thermogravimetric evaluations showed that once the hydration reaction resumed, the retardation effect of the surfactant did not have a negative impact on the amount of hydration products precipitated. It was concluded that the commercial MWCNT dispersion presents a good potential to be applied in oil well cement pastes.

关键词: carbon nanotubes     surfactant     retardation     combined water     C-S-H    

Quantitative analysis of microplastics in coastal tidal-flat reclamation in Dongtai, China

《环境科学与工程前沿(英文)》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1528-5

摘要:

• Reclamation projects are important disturbances on microplastic risk in coasts.

关键词: Coastal reclamation     Engineering geotextiles     Soil microplastics     Weathering simulation     Marine emission    

Magnetohydrodynamic slip flow and diffusion of a reactive solute past a permeable flat plate with suction

Krishnendu BHATTACHARYYA, G. C. LAYEK

《化学科学与工程前沿(英文)》 2011年 第5卷 第4期   页码 471-476 doi: 10.1007/s11705-011-1130-z

摘要: The magnetohydrodynamic (MHD) boundary layer slip flow and solute transfer over a porous plate in the presence of a chemical reaction are investigated. The governing equations were transformed into self-similar ordinary differential equations by adopting the similarity transformation technique. Then the numerical solutions are obtained by a shooting technique using the fourth order Runge-Kutta method. The study reveals that due to the increase in the boundary slip, the concentration decreases and the velocity increases. On the other hand, with an increase in the magnetic field and mass suction, both boundary layer thicknesses decreased. As the Schmidt number and the reaction rate parameter increases, the concentration decreases and the mass transfer increases.

关键词: slip flow     MHD boundary layer     reactive solute diffusion     flat plate     suction/injection    

均质纤维素膜的制备及其正渗透性能研究

张兵涛,张林,黄和,侯立安

《中国工程科学》 2014年 第16卷 第7期   页码 57-61

摘要:

以纤维素(cellulose)为膜材料,离子液体1-乙基-3 甲基咪唑醋酸盐(EMIMAc)为溶剂,水为非溶剂,无纺布作为支撑层,通过相转化法制备了纤维素均质膜。采用红外、X-射线衍射和扫描电子显微镜表征了膜的结构及形貌,考察了该膜的正渗透性能。结果表明:纤维素溶解再生过程中没有发生化学变化,但晶型发生了转变;当原料液为0.6 mol/L 的氯化钠水溶液,汲取液为特制的营养液时,所制备的正渗透膜的水通量为3.534 L/(m2· h),截盐率达到99 %以上。

关键词: 正渗透     离子液体     纤维素膜     相转化     膜制备    

标题 作者 时间 类型 操作

Modeling of Ce(IV) transport through a dispersion flat combined liquid membrane with carrier P507

Liang PEI,Liming WANG,Zhanying MA

期刊论文

Enhanced cross-flow filtration with flat-sheet ceramic membranes by titanium-based coagulation for membrane

期刊论文

Electro-assisted CNTs/ceramic flat sheet ultrafiltration membrane for enhanced antifouling and separation

Shuo Wei, Lei Du, Shuo Chen, Hongtao Yu, Xie Quan

期刊论文

Experimental study on combined buoyant-thermocapillary flow along with rising liquid film on the surface

Manuel J. GOMES, Ning MEI

期刊论文

Residence time distribution and modeling of the liquid phase in an impinging stream reactor

Xingjun WANG, Xianhui HU, Lishun HU, Guangsuo YU, Fuchen WANG,

期刊论文

Preparation and characterization of PVDF-PFSA flat sheet ultrafiltration membranes

Jiquan MA, Junhong ZHAO, Zhongbin REN, Lei LI

期刊论文

A combined control strategy using tuned liquid dampers to reduce displacement demands of base-isolated

Parham SHOAEI, Houtan Tahmasebi OROMI

期刊论文

Cesium removal from radioactive wastewater by adsorption and membrane technology

期刊论文

Ionic liquid modified Pt/C electrocatalysts for cathode application in proton exchange membrane fuel

Huixin Zhang, Jinying Liang, Bangwang Xia, Yang Li, Shangfeng Du

期刊论文

Development of combined coagulation-hydrolysis acidification-dynamic membrane bioreactor system for treatment

Xue Shen, Lei Lu, Baoyu Gao, Xing Xu, Qinyan Yue

期刊论文

Numerical simulation of three-dimensional gas/liquid two-phase flow in a proton exchange membrane fuel

ZHUGE Weilin, ZHANG Yangjun, LAO Xingsheng, CHEN Xiao, MING Pingwen

期刊论文

Effect of a commercial dispersion of multi walled carbon nanotubes on the hydration of an oil well cementing

Ocar Aurelio MENDOZA REALES,William C.PEARL Jr,Maria D. M. PAIVA,CristianeR. MIRANDA,Romildo Dias TOLEDO FILHO

期刊论文

Quantitative analysis of microplastics in coastal tidal-flat reclamation in Dongtai, China

期刊论文

Magnetohydrodynamic slip flow and diffusion of a reactive solute past a permeable flat plate with suction

Krishnendu BHATTACHARYYA, G. C. LAYEK

期刊论文

均质纤维素膜的制备及其正渗透性能研究

张兵涛,张林,黄和,侯立安

期刊论文